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A novel red emitting material based on polyoxometalate@periodic mesoporous organosilica
| Title | A novel red emitting material based on polyoxometalate@periodic mesoporous organosilica |
| Publication Type | Journal Article |
| Year of Publication | 2016 |
| Authors | Granadeiro CM a, Ribeiro SO a, Kaczmarek AM b, Cunha-Silva L a, d Almeida PL c, Gago S e, Van Deun R b, de Castro B a, Balula SS a |
| Journal | Microporous and Mesoporous Materials |
| Volume | 234 |
| Pagination | 248-256 |
| ISSN | 13871811 |
| Keywords | Composite materials, Coordination environment, Efficient energy transfer, Energy transfer, Ethylene, Europium, Functionalized materials, Luminescence, Luminescent material, Mesoporous materials, Mesoporous Silica, Oxides, Periodic mesoporous organosilicas, Polyoxometalates, Rare earth elements, Red-emitting materials, Silica |
| Abstract | The first lanthanopolyoxometalate-supported bifunctional periodic mesoporous organosilica (BPMO) composite is here reported. The incorporation of decatunsgstoeuropate anions ([Eu(W5O18)2]9−) within the porous channels of an ethylene-bridged TMAPS-functionalized BPMO produced a luminescent material exhibiting a strong red emission under UV irradiation. Photoluminescence studies showed an efficient energy transfer process to the lanthanide emitting center in the material (antenna effect). A significant change in the coordination environment of Eu3+ ions was observed after its incorporation into the TMAPS-functionalized material. The possible reason for this is discussed within the paper. © 2016 Elsevier Inc. |
| URL | https://www.scopus.com/inward/record.uri?eid=2-s2.0-84979626020&doi=10.1016%2fj.micromeso.2016.07.023&partnerID=40&md5=3b9517f52a4e1268d746d3f3ec881da9 |
| DOI | 10.1016/j.micromeso.2016.07.023 |
